Standard electrode potential of sodium

Standard electrode potential, Tafel equation, and the solvation thermodynamics.

Equilibrium in the electronic subsystem across the solution-metal interface is considered to connect the standard electrode potential to the statistics of localized electronic states in solution. We argue that a correct derivation of the Nernst equation for the electrode potential requires a careful separation of the relevant time scales. An equation for the standard metal potential is derived ...

The standard hydrogen electrode and potential of zero charge in density functional calculations

Methods to explicitly account for half-cell electrode potentials have recently appeared within the framework of density functional theory. The potential of the electrode relative to the standard hydrogen electrode is typically determined by subtracting the experimental value of the absolute standard hydrogen electrode potential (ASHEP) from the calculated work function. Although conceptually co...

Standard hydrogen electrode and potential of zero charge in density functional calculations

RATE CONSTANTS FUR THE ELECTRODE REACTIONS OF QUINONES IN CHLOROFORM: THE DEPENDENCE ON ELECTRODE MAmRIAL,S AND APPARENT STANDARD POENTIALS

The reduction process for some quinones has been studid by cyclic voltammeby, rotating disk electrode voltammetry and chronopotentiometry in chloroform at platinum, gold and glassy carbon electrodes using tetrabutylmonium perchlorate (TB AP) as supporting eiectrolyte. The results obtained from this study reveal that the reduction of the quinones is two one-electron processes, the first redu...

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries

Lithium (Li)-ion batteries (LIB) have governed the current worldwide rechargeable battery market due to their outstanding energy and power capability. In particular, the LIB’s role in enabling electric vehicles (EVs) has been highlighted to replace the current oil-driven vehicles in order to reduce the usage of oil resources and generation of CO 2 gases. Unlike Li, sodium is one of the more abu...